Stefano Merlino : EMU 1 - Modular Aspects of Minerals

Stefano Merlino : EMU 1 - Modular Aspects of Minerals

From the Preface

Since the first beginning of the crystal chemical study of the inorganic compounds, a simple modular approach was developed, by looking at the crystal structures as built up through the assembling of polyhedral units. This approach was not only useful for a vivid and insightful description of the complex atomic arrangements of natural and synthetic compounds, but, through the use of simple and powerful rules for assembling the polyhedral units, it displayed an extraordinary heuristic power, suggesting reliable models for many complex structural assemblages. The polyhedral approach also laid the basis for meaningful classifications which were applied to all the classes of inorganic compounds.

More complex modular systems were developed by applying the same theoretical scheme, namely combining polyhedral units in stable complex modules and determining the ways to firmly connect those modules. Once again useful applications were found in the three directions previously indicated:

• insightful description of complicated crystal structures;
• careful prevision of possible new assemblages;
• meaningful classifications.

For example, in looking at the large variety of zeolite structures realized in nature or in the laboratory, it clearly appears that nature and man play with a limited number of modules (rings, cages, chains) built up by the connection of the primary units (namely Si04, Al04, or, more rarely, B04, P04, Be04, ... tetrahedra). Once the kind of these modules is clarified, the description of the various structures is reduced to the 'modular play' of enumerating the various ways through which they interconnect, leading to rational classification, simple description and careful prediction. An additional vigorous stimulus to pay due attention to the modular aspects has been given by the wide access of crystal chemists to the new techniques of structural investigation offered by the electron diffraction and even more by the high resolution electron microscopy, which allow the investigation of inhomogeneities, stacking faults, microtwinning, intergrowths, domain structures, namely all those microstructural aspects which are so frequent in inorganic compounds and especially in minerals: new possible structural arrangements, as suggested by a modular approach, may in fact be present as small domains or may be realized at fault or twin boundaries.

Under the action of these various spurs the 'modular play' slowly developed into a definite research theme in crystal chemistry and the original ingenious looseness in assembling the building modules was progressively substituted by a more systematic approach with rigorous rules to select the modules and to combine them.

The most common and, therefore, the most important and investigated modular systems are those which present infinite two dimensional layers as building blocks and include OD structures, polytypes, polysomatic families, homologues series, ....

The systematic approach previously mentioned is, in all these cases, particularly evident, especially in OD structures, where rigid constraints in the choice of the modules and in their assembling are imposed by strict requirements of symmetry.

These rational, systematic approaches now provide us with reliable procedures to effectively deal with modular problems and therefore it seems necessary that these procedures be part of the cultural equipment of every crystal chemist, no matter whether active on natural or synthetic products. The lectures held at the School on Modular Aspects of Minerals, collected in the five chapters of this volume, have just the aim to show the wide range of modular problems in mineralogy and to indicate the procedures to deal with them.

Stefano Merlino

Contents of Volume 1

Preface of the editor by S. MERLINO

Chapter 1. OD theory: fundamentals and application

• Fundamentals of the OD theory by S. DUROVIC)
• OD approach in minerals: examples and applications by ST. MERLINO

Chapter 2. Modular aspects of layer silicates

• Theoretical deviation and identification of possible two-layer lizardite polytypes by I. DÓDONY
• Crystallography of mica polytypes by M. NESPOLO, H. TAKEDA, G. FERRARIS)
• Equilibrium and kinetic processes for polytype and polysome generation by A. BARONETT
• Mixed layer minerals by V. A. DRITS

Chapter 3. Modular aspects of sulfides and sulfosalts

• Modular structures in sulfides: sphalerite / wurtzite- pyrite / marcasite- and pyrrhotite-type minerals by M. PÓSFAI, P.R. BUSECK
• Modular and crystal chemistry of sulfosalts and other complex sulfides by E. MAKOVICKY

Chapter 4. Polysomatic approach in minerals: examples and applications

• Polysomatism as a tool for correlating properties and structure by G. FERRARIS
• Polysomatic approach in the crystal chemical study of minerals by S. MERLINO, M. PASERO

Chapter 5. Different approaches to modularity

• Modular analysis of crystal structures by B. B. ZVYAGIN
• Structural aspects of oxide and oxysalt minerals by F. C. HAWTHORNE
• Name and subject index